Macor – Machinable Ceramic

Macor machinable ceramics are white, odorless, and non wetting ceramics produced by Corning Inc. Macor has zero porosity, zero gas release rate, low thermal expansion coefficient, and the ability to process like metals. In application scenarios that require high performing and vacuum environments, Macor is usually machined into high-precision, complex irregular components to ensure the reliability and stability of the project. Through polishing, the surface roughness of these components can reach a low value of Ra 0.013 μ m. In addition, Macor's advantage is that it can be machined using standard metalworking tools without sintering or high-temperature treatment. Compared with other technical ceramics, its machining flexibility undoubtedly makes it stand out in applications with complex shapes and high precision requirements.

Macor Advantages

  • Macor has a pore free microstructure, making it impermeable to gases and liquids. Performed well in Ultra High Vacuum

  • Excellent machinability, which can be processed using standard metal processing tools such as lathes, milling machines, drills, and saws.

  • No sintering or further heat treatment is required, reducing manufacturing costs.

  • Can be combined with other materials such as metal and glass

  • Not easy to creep or deform at high temperatures, with good dimensional stability

  • Electric insulator material, it is an ideal material for electronic components and high-voltage applications

  • Low thermal expansion coefficient, The coefficient of thermal expansion matches many metals and sealing glasses

  • Has strong resistance to various chemical substances, including acids, bases, solvents, and gases

  • Capable of continuous operation at temperatures up to 800 ° C, with a peak operating temperature of 1000 ° C under no-load conditions

  • In high-precision and complex applications, Macor can achieve a machining tolerance of 0.0005 inches (0.013 millimeters)


What can Macor ceramics be used for


  • Ultra high vacuum system, vacuum feedthrough, and insulator

  • Fixtures, insulators, and precision components in semiconductor equipment

  • Mass spectrometer, ion trap, and low-temperature system

  • Surgical instruments, diagnostic equipment, and imaging system components

  • Electric insulators in ion thrusters

  • Electrode holder for plasma generator

  • Structural support for high-voltage equipment and transformers

  • High voltage components in X-ray tubes

  • Optical components in spectrometers and laser systems

  • High temperature insulation brackets and components in spacecraft and satellites


Products

Macor Material Characteristics

Thermal

SI/Metric

Imperial

CTE -100°C - 25°C

81 x 10-7/°C

45 x 10-7/°F

CTE 25°C  - 300°C

90 x 10-7/°C

50 x 10-7/°F

CTE 25°C  - 600°C

112 x 10-7/°C

62 x 10-7/°F

CTE 25°C  - 800°C

123 x 10-7/°C

68 x 10-7/°F

Specific Heat, 25°C

0,79 kJ/kg°C

0.19 Btu/lb°F

Thermal Conductivity, 25°C

1,46 W/m°C

10.16 Btu.in/hr.ft²°F

Thermal Diffusivity, 25°C

7,3 x 10-7m²/s

0.028 ft²/hr

Continuous Operating Temperature

800°C

1472°F

Maximum No Load Temperature

1000°C

1832°F

Mechanical


SI/Metric

Imperial

Density

2,52 g/cm

157 lbs/ft3

Porosity

0%

0%

Young’s Modulus, 25°C(Modulus of Elasticity)

66,9 GPa

9.7 x 106 PSI

Poisson’s Ratio

0,29

0.29

Shear Modulus, 25°C

25,5 GPa

3.7 x 106 PSI

Knoop Hardness, 100g

250 kg/mm2


Modulus of Rupture, 25°C(Flexural Strength) 

94 MPa (Minimum specified average value) 

13 600 PSI

Compressive Strength(After polishing) 

345 MPa(up to 900 MPa) 

49 900 PSI(130 000 PSI) 

Electrical


SI/Metric

Imperial

Dielectric Constant, 25°C



1 kHz 

6,01 

6,01 

8,5 GHz 

5,64

5,64

Loss Tangent, 25°C



1 kHz

0,0040 

0,0040 

8,5 GHz

0,0025

0,0025

Dielectric Strength (AC) avg. (25°C, under 0,3 mm thickness.) 

45 kV/mm

1143 V/mil

Dielectric Strength (DC) avg.(25°C, under 0,3 mm thickness) 

129 kV/mm

3277 V/mil

DC Volume Resistivity, 25°C 

1017 Ohm.cm

1017 Ohm.cm

Disclaimer: The values presented herein represent the mean and typical outcomes derived from test samples. They are intended solely as indicative guidance for the design of ceramic components and are not guaranteed in any manner. Actual values may vary based on the shape and size of the intended component. 

Machining Macor

Machining Macor (glass ceramics) requires special techniques to obtain precise dimensions and smooth surfaces. Careful attention should be paid to tool selection, cutting parameters, and cooling methods. Tool selection: Use standard hard alloy tools to ensure cutting accuracy. Machine settings: Ensure strict machine settings to minimize vibrations that may cause debris and cracks. Cooling: Use coolant to dissipate heat and reduce thermal stress. Processing Macor ceramics, especially complex structural components, requires a comprehensive understanding of material properties and professional processing techniques. By carefully selecting tools, optimizing processing parameters, and adopting advanced technology, high-precision and high-quality components are achieved to meet the strict requirements of various high-performance applications.



Jundro Ceramics is a professional precision manufacturer of Macor Machinable Ceramic materials. We specialize in utilizing our technical expertise and advanced equipment to process high-precision products. Our comprehensive service scope includes material selection, precision machining, surface treatment, and quality testing to ensure that each product can perform at its best in practical applications. If you would like to purchase Macor boards, rods, bars, tubes, or custom machined parts, please contact us


Request For Quote

Industry Applications

Frequently Asked Question

ask

What size of macor products can we process?

Q:

At present, Corning can only provide two specifications of Macor materials: 330*350*57mm (approximate size) and φ76mm*317mm. Junjie

Ceramics has a very rich experience in the processing of Macor machinable ceramics, and can process products within the full size range of the above two specifications. 

We have 8 CNC machining centers for high-precision ceramics, as well as five-axis machining centers. The Macor ceramic products we process include: ion trap lens holders, four-stage rod 

ceramic holders, insulators, etc.


Machining accuracy


Flatness: 0.001mm


Dimensional tolerance: 0.001mm


Roughness: Ra0.01um



ask

What are the glass ceramic materials

Q:

Glass ceramic materials are a type of material that generates small crystals in a glass matrix through specific heat treatment processes. They have the transparency of glass and excellent mechanical and thermal properties of ceramics. Common glass ceramic materials include the following:

  • Zerodur Glass Ceramic

  • Lithium aluminum silicate (LAS) glass ceramics

  • Aluminum silicate glass ceramics

  • Silicon nitride glass ceramic

  • Phosphate glass ceramics

  • Machinable glass-ceramic

These glass ceramics are widely used in optical instruments, aerospace, electronics, and medical fields


ask

The Use of Macor in Processing Glass Ceramics

Q:

Macor machinable glass ceramics were originally designed for NASA's space shuttle to prevent heat transfer from the outside to the interior of the shuttle. Due to its electrically 

insulating and thermal insulation properties, it was used in the window frames of the space shuttle; Macor is radiation resistant and porosity free (porosity is zero), and it does not emit 

vapors of any kind (toxic or otherwise) even at the lower pressures found in spacecraft. As a result, Macor was later used in many high vacuum environments, making it an excellent material 

for vacuum applications such as electron microscopy.

Main Applications:

Electronics/Semiconductors

Precision coil holder (high precision, dimensional stability)

High-voltage insulators (smooth and unaffected by arcing)


Laser applications

Gaskets, cavities and reflectors in laser assemblies (precision surface treatment and heat resistance)


High vacuum applications

Thermal fracture in high-temperature processing equipment.

Coil holder and vacuum feed-through (vacuum-stable and hermetically sealable)


Aerospace/space industry

NASA space shuttle hinges, fixing rings on doors and windows

Brackets and components (thermally and electrically insulated) in multiple spaceborne systems


Nuclear industry

Fixtures and reference blocks in power generation units (dimensions independent of irradiation)


ask

The difference between Macor and alumina ceramic

Q:

There is a clear difference between Macor and alumina ceramics. Compared with alumina ceramics, Macor has the characteristics of low processing cost and strong plasticity.

 Alumina ceramics are a kind of hard technical ceramics, which are processed with diamond grinding tools for grinding.


The processing cost is relatively high. Here are the main differences between the two materials that can be considered when choosing between Macor and Alumina.


Operating temperature


The maximum operating temperature of Macor is 800°C; The maximum operating temperature of alumina is 1000°C.


Abrasion resistance


The same machinable properties of Macor mean that it is relatively less resistant to wear compared to alumina.


cost


For smaller quantities, Macor offers a better value for money.


ask

Material composition of Macor

Q:

Macor is mainly composed of fluorocrystalline mica and borosilicate glass, which is a composite material. The two main ingredients account for about 45% and 55% respectively. Here are its main chemical components:


46% Silicon Dioxide (SiO2)


17% Magnesium Oxide (MgO)


16% Alumina (Al2O3)


10% potassium (K2O)


7% Boron (B2O3 )


4% fluorine (F)


ask

Macor Ceramic Material Machining

Q:

Macor machinable glass-ceramic can be easily machined with standard metalworking tools, rendering it suitable for the fabrication of complex, high-precision components. The following are essential guidelines for machining this material:

It is recommended to utilize carbide or polycrystalline diamond (PCD) cutting tools to achieve optimal results. Additionally, it is essential to maintain sharp edges to mitigate the risk of material chipping.

The machining speeds should be maintained at moderate levels, generally ranging from 300 to 1000 revolutions per minute (RPM), while the feed rate should be set between 0.002 and 0.005 inches per revolution for both turning and milling processes.

The machining process can be conducted without coolant; however, the application of water-soluble coolant enhances the surface finish and minimizes tool wear.

It is advisable to provide a small machining allowance for subsequent grinding or polishing processes. Typical tolerances of ±0.0005 inches can be attained.

For achieving finer surface finishes, it is advisable to employ diamond grinding and polishing subsequent to the rough machining process.

By adhering to these guidelines, Macor components can be precisely machined into complex shapes while preserving their inherent properties.


ask

What is Macor

Q:

Macor is a high-performance machinable glass ceramic developed by Corning Inc. Known for its unique processability, it is suitable for various industry applications. Macor has a temperature resistance of up to 1000 ° C and excellent electrical insulation performance, and is commonly used in aerospace, electronics, and medical device manufacturing.


One of the prominent features of Macor is its processability. Macor can be easily formed and manufactured using standard machining tools, enabling complex designs and precise tolerances. This ability greatly shortens production time and costs, making it the preferred material for prototypes and customized components.


In addition, Macor exhibits characteristics suitable for ultra-high vacuum (UHV) environments, which benefits from its pore free microstructure. And excellent chemical stability.


ask

What are the differences between Macor and Shapal?

Q:

 Both Macor and Shapal Hi M Soft are machinable glass ceramics with good machinability. Nevertheless, there are significant differences between the two materials, especially in terms of thermal and mechanical 

properties. The following are the material differences sorted out by Junjie Ceramics for your reference when purchasing. 


Visibility

Macor was born earlier than shapal and has a wider range of applications, so the former is much more well-known than the latter. In China, there is no agent of shapal materials, and materials can only

be purchased from abroad,and Junjie is one of the few processors in China.


Thermal conductivity

Thermal conductivity is the most significant difference between the two materials, and Macor is a thermal insulator with a thermal conductivity of only 1.46 W/(m K) that can be used as an insulating medium

Shapal Hi M,on the other 

hand, is a heat conductor with a thermal conductivity of up to 90 W/(m K) 

(close to silicon carbide ceramics). Therefore, if thermal conductivity is your key consideration when choosing these two materials, I believe you can now make a quick judgment.


Thermal shock

There is also a clear difference between Macor and Shapal in terms of thermal shock resistance. While Makor is prone to chipping when subjected to rapid hot and cold cycles, the Shapal is much better at this.

 Therefore, if the use environment often requires thermal cycling, there is no doubt that Shapal is a better choice.


Maximum temperature

The maximum operating temperature of the Makor is 800°C (in an air atmosphere) and the maximum operating temperature of the Shapal can reach 1900°C (in an inert atmosphere).


Mechanical strength

Shapal has better flexural strength (300 vs. 94 MPa) as well as better compressive strength (1200 vs. 345 MPa) compared to Macor.


Cost of use

Macor is a relatively cost-effective material from a material cost perspective, which is why Macor has a much higher market share than Shapal Hi M Soft, so when both materials meet the design needs, 

Macor is a better choice.


Dongguan Jundro ceramics Technology Co.,Ltd

E-mail:info@jundro.com

Tel:+86-769-82913501

Fax:+86-769-82913801

Add: Room 306, Gate B, Unit 1, Block 2 South, No. 1 Yile Road, Songshan Lake, Dongguan City, Guangdong Province, China(523808)

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